二烃基硼酸
二烃基硼酸的结构通式
二烃基硼酸 是硼酸 的两个羟基被烃基取代得到的有机硼化合物 ,其通式为R2 BOH。它的羟基氢被烃基取代,可以得到二烃基硼酸酯 (R2 BOR')。
二烃基硼酸及其衍生物
常见的物质见列表:
R2 BOR'
酸 R'=H
酸酐
酯R'
R
氢(H)
氧(-O-)
氨基乙基
乙基
正丙基
正丁基
3-甲基丙基
1-甲基丙基
苯基
乙二氧二基
甲基
8-喹啉基
苯基
Y
[ 1]
Y cas 524-95-8
Y cas 43185-52-0
Y
Y cas 15323-04-3
Y
Y
Y
Y cas 13471-36-8
SID 535455
o-甲苯基
Y
Y
m-甲苯基
Y
p-甲苯基
Y [ 2]
Y
p-茴香基
Y
Y [ 3]
Y
p-联苯基
Y
Y [ 4]
Y
p-氯苯基
Y cas 89566-59-6
Y [ 5]
Y cas 61733-90-2
Y cas 564483-61-0
3-氯苯基
Y cas 433338-06-8
α-萘基
Y
Y [ 6]
Y [ 7] cas 6962-88-5
β-萘基
Y
Y [ 3]
p-溴苯基
Y
Y [ 3]
Y [ 8]
2-甲基-5-氯苯基
Y
Y [ 5]
2-噻吩基
[ 9] SID 3881207
SID 8142470
mesityl
sid 4278417 CAS 20631-84-9[ 10] [ 11] [ 12]
甲基
Y cas 13061-97-7
Y cas 86610-16-4
Y cas 4443-43-0
乙基
Y cas 4426-31-7
Y [ 13] 7318-84-5
Y cas 7397-46-8
烯丙基
Y
正丁基
Y cas 1189-31-7
Y [ 14]
cas 19324-14-2
Y cas 2344-21-0
Y
Y
Y
Y
Y
Y cas 2344-21-0
4-甲基丁基
Y
2-氯乙烯基
Y
Y [ 15]
3,5-二甲基苯基
Y [ 16]
丙基
Y cas 53678-60-7
Y cas 2938-89-8
1-甲基丙基
cas 4026-69-1
2-甲基丙基
cas 4026-82-8
参考文献
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^ Kuhlmann, Matthias; Baumgartner, Thomas; Parvez, Masood. A new polymorph of dimesitylborinic acid . Acta Crystallographica Section E. 7 June 2008, 64 (7): o1185. PMC 2961869 . PMID 21202827 . doi:10.1107/S1600536808015638 .
^ Weese, Kenneth J.; Bartlett, Ruth A.; Murray, Brendan D.; Olmstead, Marilyn M.; Power, Philip R. Synthesis and spectroscopic and structural characterization of derivatives of the quasi-alkoxide ligand [OBMes2]- (Mes = 2,4,6-Me3C6H2). Inorganic Chemistry. 1 July 1987, 26 (15): 2409–2413. doi:10.1021/ic00262a015 .
^ Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF) . August 1960 [5 October 2013] . (原始内容 (PDF) 存档于2016-03-05). ref 28
^ Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF) . August 1960 [5 October 2013] . (原始内容 (PDF) 存档于2016-03-05). ref 17
^ Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF) . August 1960 [5 October 2013] . (原始内容 (PDF) 存档于2016-03-05). ref 29
^ Winkle, D. boronic acids can be used as viable alternatives to borinic acids in suzuki coupling reactions . Organic Process Research & Development. 2001, 5 (4): 450–451. doi:10.1021/op010207s . [失效連結 ]