Teknesium(VII) sulfida
| Nama | |
|---|---|
| Nama lain
Teknesium heptasulfida, diteknesium heptasulfida
| |
| Penanda | |
| Nomor EC | |
| Nomor RTECS | {{{value}}} |
| Sifat | |
| S7Tc2 | |
| Massa molar | 420,42 g·mol−1 |
| Penampilan | kristal berwarna cokelat tua |
| tak larut | |
| Senyawa terkait | |
Senyawa terkait
|
Renium(VII) sulfida |
Kecuali dinyatakan lain, data di atas berlaku pada suhu dan tekanan standar (25 °C [77 °F], 100 kPa). | |
| Referensi | |
Teknesium(VII) sulfida merupakan senyawa kimia anorganik biner dari logam teknesium dan belerang dengan rumus kimia Tc2S7.[1][2][3][4]
Sintesis
Melewatkan hidrogen sulfida melalui larutan perteknetat asam akan menghasilkan teknesium(VII) sulfida:[5][6][7]
- 2KTcO4 + 7H2S + 2HCl → Tc2S7↓ + 2KCl + 8H2O
- 2NH4TcO4 + 7H2S + 2HCl → Tc2S7↓ + 2NH4Cl + 8H2O
Sifat kimia
Teknesium(VII) sulfida direduksi oleh hidrogen pada suhu 1000 °C:
- Tc2S7 + 7H2 → 2Tc + 7H2S
Referensi
- ^ Saiki, Y.; Fukuzaki, M.; Sekine, T.; Kino, Y.; Kudo, H. (2003). "[No title found]". Journal of Radioanalytical and Nuclear Chemistry. 255 (1): 101–104. doi:10.1023/A:1022283831945. Diakses tanggal 8 Juni 2025.
- ^ Zolle, Ilse (28 January 2007). Technetium-99m Pharmaceuticals: Preparation and Quality Control in Nuclear Medicine (dalam bahasa Inggris). Springer Science & Business Media. hlm. 207. ISBN 978-3-540-33990-8. Diakses tanggal 8 Juni 2025.
- ^ Advances in Inorganic Chemistry and Radiochemistry (dalam bahasa Inggris). Academic Press. 1968. hlm. 72. ISBN 978-0-08-057860-6. Diakses tanggal 8 Juni 2025.
- ^ Cohen, M. B.; Spolter, L.; Szymendera, J.; Radwan, M. (April 1972). "Rhenium and technetium heptasulfide". Journal of Nuclear Medicine. 13 (4): 287–288. ISSN 0161-5505. PMID 5011784. Diakses tanggal 8 Juni 2025.
- ^ Boschke, Friedrich L. (31 Desember 1981). Inorganic Chemistry (dalam bahasa Inggris). Walter de Gruyter GmbH & Co KG. hlm. 131. ISBN 978-3-11-270829-3. Diakses tanggal 8 Juni 2025.
- ^ "CharChem. Technetium(VII) sulfide". easychem.org. Diakses tanggal 8 Juni 2025.
- ^ Poineau, Frederic; Burton-Pye, Benjamin P.; Sattelberger, Alfred P.; Czerwinski, Kenneth R.; German, Konstantin E.; Fattahi, Massoud (2018). "Speciation and reactivity of heptavalent technetium in strong acids". New Journal of Chemistry. 42 (10): 7522–7528. doi:10.1039/c7nj04912a. Diakses tanggal 8 Juni 2025.
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